Peracetic Acid (CH₃CO₃H)

CAS Number: 79-21-0
Peracetic acid (PAA, CH₃CO₃H) is a highly reactive oxidizing agent and disinfectant used extensively in food and beverage processing, healthcare sterilization, water treatment, and the pharmaceutical industry. It has a pungent, acrid vinegar-like odor detectable at very low concentrations. Peracetic acid is a strong irritant to the eyes, skin, and respiratory tract, and at higher concentrations can cause pulmonary edema and severe chemical burns. It is also a sensitizer that can cause occupational asthma. Workers in food processing facilities, hospitals using PAA-based sterilizers, and water treatment plants face the greatest exposure risk.

Peracetic acid (PAA) vapor monitoring helps confirm worker safety during disinfection and sterilization when PAA-based chemicals are used and airborne levels can rise quickly. RAECO Rents gas monitors are bump tested or span calibrated on the day of shipment. Our team can help confirm the right monitor, alarms, and setup for the job, with fast turnaround and phone support so you can get reliable field readings quickly.

Regulatory Exposure Limits

Updated on April 03, 2026

OSHA PEL
TWA: No established PEL
STEL: N/A
C: N/A
NIOSH REL
TWA: No established REL
STEL: N/A
C: N/A
IDLH: 0.64 ppm (1.7 mg/m³)
ACGIH TLV
TWA: N/A
STEL: 0.4 ppm (inhalable fraction and vapor) [2013]
C: N/A
Frequently Asked Questions
Common questions about
What can peracetic acid (PAA) monitoring help me decide?
PAA monitoring helps verify local exhaust effectiveness, confirm safe work practices during handling, set re-entry timing after cycles, and decide whether added ventilation or enclosure is needed.
When do I need continuous PAA monitoring?
During tasks where concentrations can spike quickly (chemical handling, equipment opening, cycle start/stop) and during the re-entry window after a cycle. Continuous data helps you see whether peaks occur at predictable moments.
What should I know before renting PAA monitoring equipment?
Confirm where PAA is used (open handling vs. enclosed equipment), the ventilation conditions, whether workers are present during sterilization cycles, and whether you need logged data for reporting. Also check whether other oxidizers are present that might require a more specific detection approach.
Where should PAA monitors be placed to capture real exposure risk?
Place monitors in the breathing zone for personal exposure decisions and near likely release points for process troubleshooting. Avoid placing the only monitor in a fresh-air supply stream — it will under-represent actual worker exposure where PAA concentrations are highest.
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